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Table 2 Chemical and isotopic compositions of the estimated KDE, the Arima brine end-member, and fluid inclusions within metamorphic rocks in a subduction zone

From: Original composition and formation process of slab-derived deep brine from Kashio mineral spring in central Japan

 

Temperature, °C

pH

Na, mg/L

K, mg/L

Mg, mg/L

Ca, mg/L

Cl, mg/L

HCO3, mg/L

SO4, mg/L

Li, mg/L

Br, mg/L

Br/Cl, molar ratio, × 10−3

δD, ‰

δ18O, ‰

References

KDE

12

7.8

14,000

180

66

650

24,000

66

0

83

41

0.75

− 52

− 2

Present study

Arima end-member

>138

25,900

5250

0.09

5020

54,000

78

115

0.92

− 32

10

Masuda et al. (1985)

21,000

3700

3100

42,000

55

84

2.0

− 33

6

Kusuda et al. (2014)

Fluid inclusions

600 ~ 3700

12,000 ~ 240,000

27 ~ 2000

1.0 ~ 3.7

Kendrick et al. (2011)

5400 ~ 53,000

1100 ~ 57,000

N.D. ~ 20,000

N.D. ~ 16

N.D. ~ 49

Fukuyama et al. (2017)

  1. KDE is extrapolated as described in the text. The composition of the Arima brine end-member is from Masuda et al. (1985) and Kusuda et al. (2014), and those of fluid inclusions are from Kendrick et al. (2011) and Fukuyama et al. (2017)