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Table 2 Chemical and photochemical reaction of \(\hbox {Ca}^+\)

From: First simulations of day-to-day variability of mid-latitude sporadic E layer structures

Reaction

\(^{1}\)Rate coefficient

References

\(O_2^+ + Ca \rightarrow Ca^+ + O_2\)

\(k_{18} = 1.8\times 10^{-15}\)

Rutherford et al. (1972)

\(NO^+ + Ca \rightarrow Ca^+ + NO\)

\(k_{19} = 4.6\times 10^{-15}\)

Rutherford et al. (1972)

\(Ca^+ + e^- \rightarrow Ca + hv\)

\(k_{20} = 3.8\times 10^{-18}(\frac{T_e}{200})^{-0.9}\)

Shull and van Steenberg (1982)

\(Ca + hv \rightarrow Ca^+ + e^-\)

\(^{2}\) \(k_{21} = 5.0\times 10^{-5}\)

Plane et al. (2018)

  1. \({}^{1}\) Units: unimolecular, \(\hbox {s}^{-1}\); bimolecular, \(\hbox {cm}^3\) \(\hbox {molecule}^{-1}\) \(\hbox {s}^{-1}\)
  2. \({}^{2}\) \(k_{21}\) is set to 0 if the solar zenith angle is greater than 90\(^\circ\)