# Table 1 List of reactions, nomenclature of reaction rates, branching ratios, quenching coefficients, spontaneous emission coefficients used in the paper

Reactions Coefficients/branching ratios
R1 $$\text{H}+{\text{O}}_{3}\stackrel{{\eta }_{v}{a}_{1}}{\to }{\text{OH}}_{v=5,\dots ,9}+{\text{O}}_{2}$$ $${a}_{1}/{\eta }_{v=9,\dots ,5}$$
R2 $$\text{O}+{\text{O}}_{2}+\text{M}\to {\text{O}}_{3}+\text{M}$$ $${a}_{2}$$
R3 $$\text{O}+{\text{O}}_{3}\to {2\text{O}}_{2}$$ $${a}_{3}$$
R4 $$\text{O}+{\text{OH}}_{v=5,..,9}\to {\text{O}}_{2}+\text{H}$$ $${a}_{4}\left(v=9,\dots ,5\right)$$
R5 $$\text{O}+\text{O}+\text{M}\to {\text{O}}_{2}+\text{M}$$ $${a}_{5}$$
R6 $$\text{O}+{\text{OH}}_{v\ge 5}\stackrel{{\psi }_{v}{a}_{\text{KSM}}}{\to }\text{O}{(}^{1}\text{D})+{\text{OH}}_{0\le {v}^{^{\prime}}\le v-5}$$ $${a}_{\text{KSM}}/{\psi }_{v=9,\dots ,5}$$
R7 $$\text{O}{(}^{1}\text{D})\to \text{O}+\text{h}v$$ $${A}_{\text{O}(1\text{D})}$$
R8 $$\text{O}{(}^{1}\text{D})+{\text{O}}_{2},{\text{N}}_{2},O\to \text{products}$$ $${\text{c}}_{{\text{O}}_{2}}, {\text{c}}_{{\text{N}}_{2}}, {\text{c}}_{\text{O}}$$
R9 $$\text{O}{(}^{1}\text{D})+{\text{O}}_{2}\stackrel{{\chi }_{0}{\text{c}}_{{\text{O}}_{2}}}{\to }{\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)+\text{O}$$ $${\chi }_{0}$$
R10 $$\text{O}{(}^{1}\text{D})+{\text{O}}_{2}\stackrel{{\chi }_{1}{\text{c}}_{{\text{O}}_{2}}}{\to }{\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=1\right)+\text{O}$$ $${\chi }_{1}$$
R11 $${\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=1\right)\to \text{products}+\text{h}v(\text{total})$$ $${A}_{{\text{O}}_{2}(b1)\_1}$$
R12 $${\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)\to \text{products}+\text{h}v(\text{total})$$ $${A}_{{\text{O}}_{2}(b1)\_0}$$
R13 $${\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)\to {\text{O}}_{2}+\text{h}v(762 \text{nm})$$ $${A}_{762}$$
R14 $${\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)+{\text{O}}_{2},{\text{N}}_{2},\text{O}\to \text{products}$$ $${b}_{{\text{O}}_{2}}, {b}_{{\text{N}}_{2}}, {b}_{\text{O}}$$
R15 $${\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=1\right)+{\text{O}}_{2},{\text{N}}_{2},\text{O}\to {\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)+{\text{O}}_{2},{\text{N}}_{2},\text{O}$$ $${d}_{{\text{O}}_{2}},{d}_{{\text{N}}_{2}},{d}_{\text{O}}$$
R16 $${\text{OH}}_{v} + {\text{O}}_{2} ,{\text{O}}, {\text{N}}_{2} \to {\text{OH}}_{v^{\prime} < v} + {\text{O}}_{2} ,{\text{O}}, {\text{N}}_{2}$$ $$Q_{vv^{\prime}} , P_{vv^{\prime}} , S_{vv^{\prime}}$$
R17 $${\text{OH}}_{v} \to {\text{OH}}_{v^{\prime} < v} + {\text{h}}\nu$$ $$E_{vv^{\prime}}$$