|
R1
|
\(\text{H}+{\text{O}}_{3}\stackrel{{\eta }_{v}{a}_{1}}{\to }{\text{OH}}_{v=5,\dots ,9}+{\text{O}}_{2}\)
|
\({a}_{1}/{\eta }_{v=9,\dots ,5}\)
|
|
R2
|
\(\text{O}+{\text{O}}_{2}+\text{M}\to {\text{O}}_{3}+\text{M}\)
|
\({a}_{2}\)
|
|
R3
|
\(\text{O}+{\text{O}}_{3}\to {2\text{O}}_{2}\)
|
\({a}_{3}\)
|
|
R4
|
\(\text{O}+{\text{OH}}_{v=5,..,9}\to {\text{O}}_{2}+\text{H}\)
|
\({a}_{4}\left(v=9,\dots ,5\right)\)
|
|
R5
|
\(\text{O}+\text{O}+\text{M}\to {\text{O}}_{2}+\text{M}\)
|
\({a}_{5}\)
|
|
R6
|
\(\text{O}+{\text{OH}}_{v\ge 5}\stackrel{{\psi }_{v}{a}_{\text{KSM}}}{\to }\text{O}{(}^{1}\text{D})+{\text{OH}}_{0\le {v}^{^{\prime}}\le v-5}\)
|
\({a}_{\text{KSM}}/{\psi }_{v=9,\dots ,5}\)
|
|
R7
|
\(\text{O}{(}^{1}\text{D})\to \text{O}+\text{h}v\)
|
\({A}_{\text{O}(1\text{D})}\)
|
|
R8
|
\(\text{O}{(}^{1}\text{D})+{\text{O}}_{2},{\text{N}}_{2},O\to \text{products}\)
|
\({\text{c}}_{{\text{O}}_{2}}, {\text{c}}_{{\text{N}}_{2}}, {\text{c}}_{\text{O}}\)
|
|
R9
|
\(\text{O}{(}^{1}\text{D})+{\text{O}}_{2}\stackrel{{\chi }_{0}{\text{c}}_{{\text{O}}_{2}}}{\to }{\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)+\text{O}\)
|
\({\chi }_{0}\)
|
|
R10
|
\(\text{O}{(}^{1}\text{D})+{\text{O}}_{2}\stackrel{{\chi }_{1}{\text{c}}_{{\text{O}}_{2}}}{\to }{\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=1\right)+\text{O}\)
|
\({\chi }_{1}\)
|
|
R11
|
\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=1\right)\to \text{products}+\text{h}v(\text{total})\)
|
\({A}_{{\text{O}}_{2}(b1)\_1}\)
|
|
R12
|
\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)\to \text{products}+\text{h}v(\text{total})\)
|
\({A}_{{\text{O}}_{2}(b1)\_0}\)
|
|
R13
|
\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)\to {\text{O}}_{2}+\text{h}v(762 \text{nm})\)
|
\({A}_{762}\)
|
|
R14
|
\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)+{\text{O}}_{2},{\text{N}}_{2},\text{O}\to \text{products}\)
|
\({b}_{{\text{O}}_{2}}, {b}_{{\text{N}}_{2}}, {b}_{\text{O}}\)
|
|
R15
|
\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=1\right)+{\text{O}}_{2},{\text{N}}_{2},\text{O}\to {\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)+{\text{O}}_{2},{\text{N}}_{2},\text{O}\)
|
\({d}_{{\text{O}}_{2}},{d}_{{\text{N}}_{2}},{d}_{\text{O}}\)
|
|
R16
|
\({\text{OH}}_{v} + {\text{O}}_{2} ,{\text{O}}, {\text{N}}_{2} \to {\text{OH}}_{v^{\prime} < v} + {\text{O}}_{2} ,{\text{O}}, {\text{N}}_{2}\)
|
\(Q_{vv^{\prime}} , P_{vv^{\prime}} , S_{vv^{\prime}}\)
|
|
R17
|
\({\text{OH}}_{v} \to {\text{OH}}_{v^{\prime} < v} + {\text{h}}\nu\)
|
\(E_{vv^{\prime}}\)
|
