Table 1 List of reactions, nomenclature of reaction rates, branching ratios, quenching coefficients, spontaneous emission coefficients used in the paper

R1

\(\text{H}+{\text{O}}_{3}\stackrel{{\eta }_{v}{a}_{1}}{\to }{\text{OH}}_{v=5,\dots ,9}+{\text{O}}_{2}\)

\({a}_{1}/{\eta }_{v=9,\dots ,5}\)

R2

\(\text{O}+{\text{O}}_{2}+\text{M}\to {\text{O}}_{3}+\text{M}\)

\({a}_{2}\)

R3

\(\text{O}+{\text{O}}_{3}\to {2\text{O}}_{2}\)

\({a}_{3}\)

R4

\(\text{O}+{\text{OH}}_{v=5,..,9}\to {\text{O}}_{2}+\text{H}\)

\({a}_{4}\left(v=9,\dots ,5\right)\)

R5

\(\text{O}+\text{O}+\text{M}\to {\text{O}}_{2}+\text{M}\)

\({a}_{5}\)

R6

\(\text{O}+{\text{OH}}_{v\ge 5}\stackrel{{\psi }_{v}{a}_{\text{KSM}}}{\to }\text{O}{(}^{1}\text{D})+{\text{OH}}_{0\le {v}^{^{\prime}}\le v-5}\)

\({a}_{\text{KSM}}/{\psi }_{v=9,\dots ,5}\)

R7

\(\text{O}{(}^{1}\text{D})\to \text{O}+\text{h}v\)

\({A}_{\text{O}(1\text{D})}\)

R8

\(\text{O}{(}^{1}\text{D})+{\text{O}}_{2},{\text{N}}_{2},O\to \text{products}\)

\({\text{c}}_{{\text{O}}_{2}}, {\text{c}}_{{\text{N}}_{2}}, {\text{c}}_{\text{O}}\)

R9

\(\text{O}{(}^{1}\text{D})+{\text{O}}_{2}\stackrel{{\chi }_{0}{\text{c}}_{{\text{O}}_{2}}}{\to }{\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)+\text{O}\)

\({\chi }_{0}\)

R10

\(\text{O}{(}^{1}\text{D})+{\text{O}}_{2}\stackrel{{\chi }_{1}{\text{c}}_{{\text{O}}_{2}}}{\to }{\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=1\right)+\text{O}\)

\({\chi }_{1}\)

R11

\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=1\right)\to \text{products}+\text{h}v(\text{total})\)

\({A}_{{\text{O}}_{2}(b1)\_1}\)

R12

\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)\to \text{products}+\text{h}v(\text{total})\)

\({A}_{{\text{O}}_{2}(b1)\_0}\)

R13

\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)\to {\text{O}}_{2}+\text{h}v(762 \text{nm})\)

\({A}_{762}\)

R14

\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)+{\text{O}}_{2},{\text{N}}_{2},\text{O}\to \text{products}\)

\({b}_{{\text{O}}_{2}}, {b}_{{\text{N}}_{2}}, {b}_{\text{O}}\)

R15

\({\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=1\right)+{\text{O}}_{2},{\text{N}}_{2},\text{O}\to {\text{O}}_{2}\left({b}^{1}{\Sigma }_{g}^{+},v=0\right)+{\text{O}}_{2},{\text{N}}_{2},\text{O}\)

\({d}_{{\text{O}}_{2}},{d}_{{\text{N}}_{2}},{d}_{\text{O}}\)

R16

\({\text{OH}}_{v} + {\text{O}}_{2} ,{\text{O}}, {\text{N}}_{2} \to {\text{OH}}_{v^{\prime} < v} + {\text{O}}_{2} ,{\text{O}}, {\text{N}}_{2}\)

\(Q_{vv^{\prime}} , P_{vv^{\prime}} , S_{vv^{\prime}}\)

R17

\({\text{OH}}_{v} \to {\text{OH}}_{v^{\prime} < v} + {\text{h}}\nu\)

\(E_{vv^{\prime}}\)