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Table 3 Calibration condition, intensities of m/z 28 and 40, and sensitivity of 40Ar

From: The GAs Extraction and Analyses system (GAEA) for immediate extraction and measurements of volatiles in the Hayabusa2 sample container

Calib. No

Date

Volume of meas.a

Pressure in QMSb (Pa)

Amount of 40Ar in QMS (cm3STP)

I40 (A)

I28/I40

Sensitivity of 40Arc (cm3STP/A)

8

7/8/20

PQ-

1.5E−05

4.37E−10

1.02E−12

120

428

9

7/14/20

PQ-

1.5E−05

4.33E−10

1.03E−12

136

421

10 (a)

7/21/20

PQ-

1.5E−05

4.29E−10

6.90E−13

95

621

10 (b)

 

V2-

3.1E−05

1.00E−09

1.99E−12

111

458

10 (c)

 

Vga-

6.6E−05

2.65E−09

4.05E−12

106

507

11 (a)

8/18/20

PQ-

1.5E−05

4.25E−10

6.23E−13

82

682

11 (b)

 

V2-

3.1E−05

9.96E−10

1.72E−12

89

524

11 (c)

 

V1-

2.5E−05

8.74E−10

1.30E−12

98

559

11 (d)

 

Vga-

4.4E−05

1.75E−09

2.47E−12

108

512

12

9/16/20

PQ-

1.5E−05

4.21E−10

8.77E−13

140

480

13 (a)

 

PQ-

6.0E−06

1.73E−10

2.50E−13

69

681

13 (b)

 

Vga-

3.9E−06

1.55E−10

3.19E−13

239

345

    

Average of all data:

116

518

      

 ± 44

 ± 104

    

Average of data on 7/21 and 8/18:

98

540

      

 ± 11

 ± 77

  1. Terrestrial atmosphere was used as calibration gas. Volume fraction of 40Ar is 0.0093
  2. aVolumes to which calibration gases were introduced for the QMS measurements
  3. PQ-: [V-PQ + V-QMSW], V2-: [V-2 + V-PQ + V-QMSW], V1-: [V-1 + V-2 + V-PQ + V-QMSW], Vga-: [V-Gauge + V-1 + V-2 + V-PQ + V-QMSW]
  4. bPressures in the QMS during analyses are calculated based on the gas amounts and the volumes shown in Table 1
  5. cSensitivities are calculated using the average of three measured data around 50–90 s after inlet of gases into the QMS
  6. All sensitivities are corrected as the analytical volume conditions to be [V-PQ + V-QMSW]