Open Access

Laboratory experiments of particle size effect in X-ray fluorescence and implications to remote X-ray spectrometry of lunar regolith surface

Earth, Planets and Space200860:BF03352794

Received: 30 March 2007

Accepted: 29 October 2007

Published: 9 April 2008


We performed laboratory experiments to investigate the effect of particle size in X-ray fluorescence (XRF) with respect to interpreting remote X-ray spectrometry. To simulate microscopic roughness of the uppermost surface of lunar regolith, we used powdery specimens of crashed rocks ranging 25 to 500 μm in size and flat rock plates for comparison. Our results show that XRF intensities from powdery specimens decrease relative to those from flat plates by up to 50%, especially for larger particle size and at increasing source-to-surface-to-detector angle (phase angle). Corrections should be required for elemental analysis by XRF spectrometry in the SELENE ‘ Kaguya’ and other planetary orbiter missions.

Key words

X-ray fluorescenceparticle size effectregolithelemental compositionphase angle