Skip to main content
Earth, Planets and Space
Download PDF

Evaluation of dehydration mechanism during heating of hydrous asteroids based on mineralogical and chemical analysis of naturally and experimentally heated CM chondrites

Earth, Planets and Space volume 60, pages 855–864 (2008)Cite this article

Abstract

Based on the evidence derived from spectroscopic observation and meteorite analysis, some hydrous asteroids were heated and dehydrated for a certain period of time after aqueous alteration. In order to reproduce the dehydration processes, we experimentally heated Murchison CM chondrite at 600°C for 1 h (600°C/1 h), 600°C/96 h, 900°C/1 h, and 900°C/96 h under controlled oxygen partial pressures. The experimental products were compared with Belgica (B-)7904 CM chondrite, a meteorite from a dehydrated asteroid in terms of characteristic mineralogical and compositional properties. B-7904 shows properties intermediate between the two experimental products heated at 900°C/1 h and 900°C/96 h. In addition, the presence or the absence of some temperature-sensitive minerals in B-7904 suggests that it experienced heating at a temperature higher than 700°C but lower than 890°C. The duration of heating, based on the diffusion time needed to achieve the Fe-Mg zoning profile in olivine in B-7904, was estimated to be between 10 and 103 days at 700°C and between 1 to 102 h at 890°C. The obtained durations are much shorter than those expected from the internal heating model which requires prolonged heating over million years. Therefore, it is unlikely that the short-lived radionuclide of 26Al is a heat source for the dehydration of B-7904. Instead, short-duration local heating, such as that from impacts or solar radiation, is a more promising heat source.

References

  • Akai, J., Incompletely transformed serpentine-type phyllosilicates in the matrix of Antarctic CM chondrites, Geochim. Cosmochim. Acta, 52, 1593–1599, 1988.

    Article  Google Scholar 

  • Akai, J., Mineralogical evidence of heating events in carbonaceous chondrites, Y-86720 and Y-82162, Proc. NIPR Symp. Antarctic Meteor., 3, 55–68, 1990.

    Google Scholar 

  • Akai, J., TTT-diagram of serpentine and saponite, and estimation of meta-morphic heating degree of Antarctic carbonaceous chondrite, Proc. NIPR Symp. Antarctic Meteor., 5, 120–135, 1992.

    Google Scholar 

  • Akai, J. and T. Sekine, Shock effects experiments on serpentine and thermal metamorphic conditions in Antarctic carbonaceous chondrite, Proc. NIPR Symp. Antarctic Meteor., 7, 101–109, 1994.

    Google Scholar 

  • Beyssac, O., B. Goffé, C. Chopin, and J. N. Rouzaud, Raman spectra of carbonaceous material in metasediments: a new geothermometer, J. Metamorphic Geol., 20, 859–871, 2002.

    Article  Google Scholar 

  • Bischoff, A. and K. Metzler, Mineralogy and petrography of the anomalous carbonaceous chondrites, Yamato-86720, Yamato-82162 and Belgica-7904, Proc. NIPR Symp. Antarctic Meteor., 4, 226–246, 1991.

    Google Scholar 

  • Cuesta, A., P. Dhamelincourt, J. Laureyns, A. Martinez-Alonso, and J. M. D. Tascon, Raman microprobe studies on carbon materials, Carbon, 32, 1523–1532, 1994.

    Article  Google Scholar 

  • Deer, W. A., R. A. Howie, and J. Zussman, An Introduction to the Rock-Forming Minerals second edition, Longman Scientific and Technical, Essex, 627, 1992.

    Google Scholar 

  • Dijiken, D. K. and J. Th. M. De Hosson, Thermodynemic model of compaction of powder materials by shock waves, J. Appl. Phys., 75, 203–209, 1994.

    Article  Google Scholar 

  • Etschmann, B., A. Pring, A. Putnis, B. A. Grgyric, and A. Studer, A kinetic study of the exsolution of pentlandite (Ni,Fe)9S8 from the monosulfide solidsolution (Fe,Ni)S, Am. Mineral., 89, 39–50, 2004.

    Article  Google Scholar 

  • Fuchs, L. H., E. Olsen, and K. J. Jensen, Mineralogy, mineral chemistry, and compositions of the Murchison (C2) meteorite, Smithsonian Contr. Earth Sci., 10, 1–39, 1973.

    Article  Google Scholar 

  • Gaffey, M. J., J. F. Bell, and D. P. Cruikshank, Reflectance spectroscopy and asteroid surface mineralogy, in Asteroid II, edited by R. P. Binzel, T. Gehrels, and M. S. Matthews, 98–127, Univ. Arizona Press, Tucson, Arizona, 1989.

    Google Scholar 

  • Grimm, R. E. and H. Y. McSween, Water and thermal evolution of carbonaeous chondrite parent bodies, Icarus, 82, 244–280, 1989.

    Article  Google Scholar 

  • Hiroi, T. and M. E. Zolensky, UV-VIS-NIR absorption features of heated phyllosilicates as remote-sensing clues of thermal histories of primitive asteroids, Antarctic Meteor. Res., 12, 108–116, 1999.

    Google Scholar 

  • Hiroi, T., C. Peters, M. E. Zolensky, and P. Lipschutz, Evidence of thermal metamorphism of C, G, B, and F asteroid, Science, 261, 1016–1018, 1993.

    Article  Google Scholar 

  • Hiroi, T., C. Peters, M. E. Zolensky, and P. Lipschutz, Possible thermal metamorphism of the C, G, B, and F asteroids detected from their reflectance spectra in comparison with carbonaceous chondrites, Proc. NIPR Symp. Antarctic Meteor., 7, 230–243, 1994.

    Google Scholar 

  • Hiroi, T., C. Peters, M. E. Zolensky, and P. Lipschutz, Thermal metamor-phism of the C, G, B and F asteroids seen from the 0.7 μm, 0.3 μm, and UV absorption strengths in comparison with carbonaceous chondrites, Meteor. Planet. Sci., 31, 321–327, 1996.

    Article  Google Scholar 

  • Ikeda, Y., Petrology and mineralogy of the Yamato-82162 chondrite (CI), Proc. NIPR Symp. Antarctic Meteor., 4, 187–225, 1991.

    Google Scholar 

  • Ikeda, Y., An overview of the research consortium, “Antarctic carbonaceous chondrites with CI affinities, Yamato-86720, Yamato-82162 and Belgica-7904”, Proc. NIPR Symp. Antarctic Meteor., 5, 49–72, 1992.

    Google Scholar 

  • Jarosewich, E., Chemical analyses of meteorites: A compilation of stony and iron meteorite analyses, Meteoritics, 25, 323–337, 1990.

    Article  Google Scholar 

  • Jawhari, T., A. Roid, and J. Casado, Raman-spectroscopic characterization of some commercially available carbon-black materials, Carbon, 33, 1561–1565, 1995.

    Article  Google Scholar 

  • Katagiri, G., H. Ishida, and A. Ishitani, Raman-spectra of graphite edge planes, Carbon, 26, 565–571, 1988.

    Article  Google Scholar 

  • Kimura, M. and Y. Ikeda, Mineralogy and petrology of an unusual Belgica-7904 carbonaceous chondrites: genetic relationships among the components, Proc. NIPR Symp. Antarctic Meteor., 5, 74–119, 1992.

    Google Scholar 

  • Kitajima, F., T. Nakamura, N. Takaoka, and T. Murae, Evaluating the thermal metamorphism of CM chondrites by using pyrolytic behavior of the carbonaceous macromolecular matter, Geochim. Cosmochim. Acta, 66, 163–172, 2002.

    Article  Google Scholar 

  • MacKinnon, I. D. R. and M. E. Zolensky, Proposed structures for poorly characterized phases in C2M carbonaceous chondrite meteorites, Nature, 309, 240–242, 1984.

    Article  Google Scholar 

  • MacSween, H. Y., D. W. G. Sears, and R. T. Dodd, Thermal metamorphism, in Meteorites and the Early Solar System, edited by J. F. Kerridge and M. S. Matthews, 102–113, Univ. Arizona Press, Tucson, Arizona, 1988.

    Google Scholar 

  • Metzler, K., A. Bischoff, and D. Stöffler, Accretionary dust mantles in CM chondrite: Evidence for solar nebula processes, Geochim. Cosmochim. Acta, 56, 2873–2897, 1992.

    Article  Google Scholar 

  • Misener, D. J., Cationic diffusion in olivine to 1400°C and 35 kbar, in Geochemical Transport and Kinetics, edited by A. W. Hofmann et al., 117–129, Carnegie Inst. Washington, 1974.

    Google Scholar 

  • Miyamoto, M., Thermal metamorphism of CI and CM carbonaceous chondrites: An internal heating model, Meteoritics, 26, 111–115, 1991.

    Article  Google Scholar 

  • Miyamoto, M., N. Fujii, and H. Takeda, Ordinary chondrite parent body: An internal heating model, Proc. Lunar Planet Sci., 12B, 1145–1152, 1981.

    Google Scholar 

  • Nagao, K., K. Inoue, and K. Ogata, Primordial rare gases in Belgica-7904 (C2) Carbonaceous Chondrite, Mem. NIPR Spec. Issue, 35, 257–266, 1984.

    Google Scholar 

  • Nakamura, T., Post-hydration thermal metamorphism of carbonaceous chondrites, J. Mineral. Petrol. Sci., 100, 260–272, 2005.

    Article  Google Scholar 

  • Nakamura, T. and Y. Nakamuta, X-ray study of PCP from the Murchison CM carbonaceous chondrites, Proc. NIPR Symp. Antarctic Meteor., 9, 37–50, 1996.

    Google Scholar 

  • Nakamura, T., R. Okazaki, and G. R. Huss, Thermal metamorphism of CM carbonaceous chondrite: effects on phyllosilicate mineralogy and presolar grain abundances, Lunar Planet. Sci. Conf., 37th, 1633pdf, 2006.

    Google Scholar 

  • Nakamura, T., A. Tsuchiyama, T. Akaki, K. Uesugi, T. Nakano, A. Takeuchi, Y. Suzuki, and T. Noguchi, Bulk mineralogy and three dimensional structures of individual Stardust particles deduced from synchrotron X-ray diffraction and microtomography analysis, Meteor. Planet. Sci., 43, 247–259, 2008.

    Article  Google Scholar 

  • Ohtsuka, K., T. Sekiguchi, D. Kinoshita, J.-I. Watanabe, Y. Ito, H. Arakida, and T. Kasuga, Apollo asteroid 2005 UD: split nucleus of (3200) Phaethon?, Astron. Astrophys., 450, L25–L28, 2006.

    Article  Google Scholar 

  • Paul, R. L. and M. E. Lipschutz, Labile trace elements in some Antarctic carbonaceous chondrite: Antarctic and Non-Antarctic meteorite comparisons, Z. Naturf., A44, 979–987, 1989.

    Google Scholar 

  • Schmitt, R. T., A. Deutsch, and D. Stöffler, Calculation of hugoniot curves and post-shock temperatures for H- and L-chondrites, Lunar Planet. Sci. Conf., 25, 1209pdf, 1994.

    Google Scholar 

  • Tomeoka, K., Mineralogy and petrology of Belgica-7904: A new kind of carbonaceous chondrite from Antarctica, Proc. NIPR Symp. Antarctic Meteor., 3, 40–54, 1990a.

    Google Scholar 

  • Tomeoka, K., Phyllosilicate vein in a CI meteorite: evidence for aqueous alteration on the parent body, Nature, 345, 138–140, 1990b.

    Article  Google Scholar 

  • Tomeoka, K. and P. R. Buseck, A new layered mineral from the Mighei CM2 carbonaceous chondrite, Nature, 306, 354–356, 1983.

    Article  Google Scholar 

  • Tomeoka, K. and P. R. Buseck, Indicators of aqueous alteration in CM carbonaceous chondrites: Microtextures of a layered mineral containing Fe, S, O and Ni, Geochim. Cosmochim. Acta, 49, 2143–2163, 1985.

    Google Scholar 

  • Tomeoka, K., H. Kojima, and K. Yanai, Yamato-86720: A CM carbonaceous chondrite having experienced extensive aqueous alteration and thermal metamorphism, Proc. NIPR Symp. Antarctic Meteor., 2, 55–74, 1989a.

    Google Scholar 

  • Tomeoka, K., H. Kojima, and K. Yanai, Yamato-82162: a new kind of CI carbonaceous chondrite from Antarctica, Proc. NIPR Symp. Antarctic Meteor., 2, 36–54, 1989b.

    Google Scholar 

  • Tomeoka, K., Y. Yamahara, and T. Sekine, Experimental shock metamorphism of the Murchison CM carbonaceous chondrite, Geochim. Cosmochim. Acta, 63, 3683–3703, 1999.

    Article  Google Scholar 

  • Tomioka, N., K. Tomeoka, K. Nakamura-Messenger, and T. Sekine, Heating effects of the matrix of experimentally shocked Murchison CM chondrite: Comparison with micrometerites, Meteor. Planet. Sci., 42, 19–30, 2007.

    Article  Google Scholar 

  • Tuinstra, F. and J. L. Koenig, Raman spectrum of graphite, J. Chem. Phys., 53, 1126–1130, 1970.

    Article  Google Scholar 

  • Wang, A., P. Dhamelincourt, J. Dubessy, D. Guerard, P. Landais, and M. Lelaurain, Characterization of graphite alteration in an uranium deposit by micro-Raman spectroscopy, X-ray-diffraction, transmission electron-microscopy and scanning electron-microscopy, Carbon, 27, 209–218, 1989.

    Article  Google Scholar 

  • Yabuta, H., H. Naraoka, K. Sakanishi, and H. Kawashima, Solid-state 13C NMR characterization of insoluble organic matter from Antarctic CM2 chondrites: Evaluation of the meteoritic alteration level, Meteor. Planet. Sci., 40, 779–787, 2005.

    Article  Google Scholar 

  • Zolensky, M. E., M. Prinz, and M. E. Lipschutz, Mineralogy and thermal history of Y-82162, Y-86720 and B-7904, Papers Presented to the 16th Symposium on Antarctic Meteorites, June 5–7, Tokyo, Natl Inst. Polar Res., 195–196, 1991.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Earth and Planetary Sciences, Faculty of Sciences, Kyushu University, Hakozaki, Fukuoka, 812-8581, Japan

    Aiko Nakato, Tomoki Nakamura & Fumio Kitajima

  2. College of Science, Ibaraki University, 2-1-1 Bunkyo, Mito, 310-8512, Japan

    Takaaki Noguchi

Authors
  1. Aiko Nakato
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tomoki Nakamura
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Fumio Kitajima
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Takaaki Noguchi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Aiko Nakato.

Rights and permissions

Open Access  This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit https://creativecommons.org/licenses/by/4.0/.

Reprints and permissions

About this article

Cite this article

Nakato, A., Nakamura, T., Kitajima, F. et al. Evaluation of dehydration mechanism during heating of hydrous asteroids based on mineralogical and chemical analysis of naturally and experimentally heated CM chondrites. Earth Planet Sp 60, 855–864 (2008). https://doi.org/10.1186/BF03352837

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1186/BF03352837

Key words