Cosmic Dust: Its Formation and Evolution (III)
Magnetic ejection of diamagnetic sub-millimeter grains observed by a chamber-type μG generator orientated to identify material of a single particle
Earth, Planets and Space volume 65, pages 199–202 (2013)
A principle to identify the material of a single particle without destroying the sample is examined by an experiment in microgravity (μG). Such an identification is important as a first stage of analyzing various grains of primitive materials. The identification was based on diamagnetic susceptibility χDIA obtained from translation of the grain induced by a magnetic field. When a grain is released in an area of a monotonously decreasing field under μG conditions, it will be ejected in the direction of the field reduction; here, the area is occupied with diffused gas medium. The material identification of a primitive grain is possible by comparing the measured χDIA with published values; an intrinsic χDIA value is assigned to a material according to a molecular orbital model. We report here that the ejection is realized for sub-mm-sized crystals of various organic and inorganic materials. By developing a short drop shaft (μG duration ~0.5 s), the proposed material identification can be easily performed in an ordinary chamber. Using conventional methods, χDIA cannot be detected for a small sample of diameter below the level of a millimetre. The achieved result is a step to realize the identification of micron-sized grains that compose primitive materials.
It is generally considered that primitive materials, such as carbonaceous chondrites, are aggregates of small particles that are randomly mixed together. Such particles are composed of different materials, the estimated origins of which are heterogeneous. It is necessary to identify the materials of individual grains before performing a refined analysis of the isotopic, chemical or optical properties. Such a method of material identification should be non-destructive and easily performed. Moreover, the method should be based on a well-established physical or chemical concept.
Under conditions of normal gravity, the magnetic translation of a solid particle caused by a field gradient force has been commonly used to separate a magnetic particle composed of spontaneous magnetic moment. However, the possibility of magnetic translation has not yet been considered intensively for ordinary diamagnetic solids (Beaugnon and Tournier, 1991; Ikezoe et al., 1998). When a diamagnetic solid is placed in a gradient of a static field, with a negligible effect of gravity or viscous drag of the surrounding medium, free motion caused by the field gradient force χB(dB/dx) is expected to be observed on diamagnetic solids in common (Hisayoshi et al., 2009; Uyeda et al., 2010). This is because the material possesses an intrinsic diamagnetic susceptibility, χDIA, per unit mass, according to general considerations on the origin of diamagnetic magnetization. The diamagnetic moment has been quantitatively explained in terms of a molecular orbital method (Guputa, 1983). Hence, by comparing the observed χDIA with published values, the material of the translating particle can be identified. According to Newton’s equation of motion assumed for a field gradient force, the acceleration a of a particle is expected to be independent of the mass m of the particle in a given field distribution; it is uniquely determined by the intrinsic χDIA value of the material. This means that a χDIA measurement, thereby enabling material identification, is possible for limitlessly small samples (Uyeda et al., 2010).
In the present study, the field-induced ejection are newly observed for sub-millimeter-sized diamagnetic particles, namely graphite, bismuth and polyethylene, which have different values of χDIA. The sample was released in a μG area, of reduced pressure in a monotonously decreasing field, with a negligibly small initial velocity. The energy conservation is expected for a particle of mass m is described as ***inline eqn***. Here, the field intensity at the initial sample position is defined as B0, whereas the sample velocity, at a point where the field intensity is equal to B =0, is defined as vR. The χDIA values are directly obtained by inserting the measured values of B0 and vR in the relationship ***inline eqn***, which was derived from the conservation rule between magnetic potential and kinetic energy. The possibility of identifying the material of a single micron-sized particle is discussed, based on the experimental data.
The numerical data of the measured samples are listed in Table 1. The graphite and bismuth were both cut from synthetic material of a high quality (~99.99%). The concentration of magnetic impurity ions were below 1 ppm for both samples, according to magnetic and chemical analysis carried out in previous studies (Uyeda et al., 2010). The published χDIA values of the three materials are also listed in Table 1 (Guputa, 1983). Of these, graphite has the largest published χDIA, which is 5 × 10−6 emu/g, whereas the published χDIA of bismuth is 9.0 × 10−7 emu/g, which is an order of magnitude smaller (Guputa, 1983). The data of graphite and bismuth observed in a previous report are listed in the table (Hisayoshi et al., 2011).
The μG condition was generated by a drop shaft that had a length of 1.5 m: It was designed and constructed at the Graduate School of Science, Osaka University. The drop box had a rectangular shape with an inner size of 35 cm × 30 cm × 20 cm. The experimental setup developed to observe the magnetic ejection was installed inside the box. The setup consisted of a cylindrical Pyrex vacuum chamber coupled with a mobile sample-holder, a sample-holder controller, an IR signal receptor to operate the controller, a compact magnetic circuit and a high-vision (HV) video camera (Panasonic HDC -SD3-S). The compact magnetic circuit was assembled from a couple of Nd-Fe-B magnetic plates of size 2.5 cm × 2.0 cm × 0.6 cm. By adopting this magnetic circuit, a size reduction of the drop box became possible (Hisayoshi et al., 2011).
In order to describe the time-dependent position of the sample, x, y, z-coordinates are defined in the area of the field gradient. The field center of the attached circuit was defined as the origin of the co-ordinates. The y-axis of the coordinates was directed from the N pole to the S pole of the circuit, whereas the x-axis was parallel to the cylindrical axis of the vacuum chamber: The samples were expected to translate along the x-axis. The field distribution along the x-axis was measured prior to the experiment with a spatial division of 0.1 cm. The field intensity was equal to zero at a position of xR = 1.87 ± 0.05 cm, since the magnetic line of force turned from the [+y] to [−y] direction at this position. The experiment of magnetic ejection using the chamber-type μG generator was realized by the development of the small magnetic circuit. The initial sample position is defined as x0 for each sample. The field intensity at x = x0 is defined as B0. According to the measured field distribution, the position of x0 is in an area of negative field gradient (dB /dx < 0). The numerical values of x0 and B0 are listed in Table 1.
The drop box was attached to the ceiling of the laboratory room by an electromagnetic lock system. The free fall of the box started shortly after the power supply of the lock was switched off. The duration of μG was 0.4 seconds. After a duration of 0.05 seconds from the beginning of μG, the sample was released from the sample holder in a gas medium that was contained in the vacuum chamber. The diffused condition of the medium to minimize viscous drag was realized by reducing the gas pressure to ~100 Pa. The reduced pressure was also effective in minimizing turbulence caused by the fast movement of the sample holder. The movement of the sample along the x-axis was observed by the HV video camera from the [+z] direction. The time and spatial resolutions of the HV video camera were 0.033 s and 0.004 cm, respectively. Prior to the experiment using the chamber-type μG drop shaft, an operational test of the above-mentioned setup to observe the ejection was performed in a conventional drop shaft at the National Institute of Advanced Technology (AIST) which had a μG duration of 1.35 seconds; the gravitational acceleration was 1 Gal. It was confirmed that the image of the translation was successfully recorded within 0.4 second, which was the μG duration of the chamber-type system (gravitational acceleration was 30 Gal at after-fall 0.3 seconds).
3. Results and Discussions
The observed magnetic ejections of mm-sized diamagnetic grains were previously analyzed by an energy conservation rule between kinetic energy and field-induced potential. The χDIA values obtained from the relationship between sample velocity and field intensity, measured at different sample positions, agreed fairly well with their published values for some popular diamagnetic materials (see Fig. 2) (Uyeda et al., 2010).
Time variations of sample positions of the sub-millimeter-sized grains measured in the present study are shown in Fig. 1. As expected for diamagnetic materials, the grains of polyethylene-1 in the direction of the monotonously decreasing field (x-axis). Velocity at xR was vR = 5.62 cm/s for polyethylene-1. The χDIA values are calculated with the above-mentioned relationship ***inline eqn***. The χDIA values obtained from the above relationship are compiled in Table 1 and Fig. 2 for the three materials. It is seen that measured values agree fairly well with their published values. The reduction of sample velocity due to gas friction is estimated to cause an error of about 3% in the obtained χDIA values. It is confirmed from Table 1 that no significant tendency of mass dependence is seen for the χDIA values, between two different samples composed of the same material. According to Fig. 2, the range of χDIA observed in the present study almost coincides with the range of published χDIA values compiled in a data book (Guputa, 1983). It may be considered, therefore, that material identification is possible for a sub-millimeter-sized solid, in general, by observing the magnetic ejection.
It was pointed out that the χDIA measurement based on the above-mentioned magnetic ejection is free of a background signal of the sample holder; it is also free of a mass measurement of the sample (Uyeda et al., 2010). In the conventional method, the minimum size of a measurable sample was limited by the above-mentioned two factors. This means that, in principle, magnetic susceptibility is obtained on samples of a limitlessly small size, as long as the motion of the sample can be detected. The lower limit of the sample size may reach several microns by introducing an optical microscope in the drop box. Accordingly, the identification of an individual grain, based on the above χDIA measurements, will become possible for a micron-size particle.
As mentioned before, a non-destructive method to identify the material of a single particle without destroying the sample is desired at the first stage of analyzing primitive grains. Up to now, such a method has not been established. The present results achieved on sub-millimetre-sized diamagnetic grain have a large significance as a step to realize the identification of micron-sized grains that compose the primitive materials. The technique described is useful in the search for new types of pre-solar grains that are as yet identified.
In μG conditions, field-induced translation is commonly expected to occur on a single sub-millimeter-sized solid. The translation is independent of the mass of the particle because the field gradient force is a volume force that is derived from the localized electrons of individual atoms. A field-induced translation of an ordinary solid, free of spontaneous moment, has not been previously recognized.
In a given field distribution, the induced velocities are determined by the value of χDIA. The value of χDIA is obtained for a limitlessly small grain, provided that its motion is observable. The present size of observable size is 100 μm. Material of a single sub-millimeter-sized particle is expected to be identified non-destructively, simply by observing the translation. This is because a material generally possesses an intrinsic χDIA value.
The field-induced motion is observable using a chamber-type μG generator, which was realized by introducing small Nd-Fe-B plates. The material identification of a single grain that composes primitive materials becomes possible by a routine process that can be performed in an ordinary laboratory. Such non-destructive identification is important as a primary stage of refined analysis on various samples.
Beaugnon, E. and R. Tournier, Levitation of organic materials, Nature, 349, 470, 1991.
Guputa, R., Landort Bornstein, New Series, 44, 1983.
Hisayoshi, K., S. Kanou, and C. Uyeda, Diamagnetic susceptibility of single micro-particles detected by free translational motions in field gradient, J. Phys.: Conf. Ser., 156, 012021, 2009.
Hisayoshi, K., C. Uyeda, K. Kuwada, M. Mamiya, and H. Hagai, Magnetic ejection of submilimeter-sized diamagnetic grains observed in a chamber-type drop shaft, J. Phys.: Conf. Ser., 327, 012058, 2011.
Ikezoe, Y., N. Hirota, J. Nakagawa, and K. Kitazawa, Nature, 393, 749, 1998.
Uyeda, C., K. Hisayoshi, and S. Kanou, Magnetic ejection and oscillation of diamagnetic crystals observed in microgravity, J. Phys. Soc. Jpn., 79, 064709, 2010.
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Hisayoshi, K., Uyeda, C., Kuwada, K. et al. Magnetic ejection of diamagnetic sub-millimeter grains observed by a chamber-type μG generator orientated to identify material of a single particle. Earth Planet Sp 65, 199–202 (2013). https://doi.org/10.5047/eps.2012.08.010
- Magnetic ejection
- chamber-type drop shaft