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Remanence cycling of 0.6–135 µm magnetites across the Verwey transition
© The Author(s) 2018
- Received: 11 July 2018
- Accepted: 18 September 2018
- Published: 4 October 2018
- Verwey transition
- Saturation remanence
- Low-temperature cycling
Magnetite (Fe3O4) is cubic at room temperature with inverse spinel structure. Its first magnetocrystalline anisotropy constant K1 is negative and the easy axes for spontaneous magnetization Ms are the four 〈111〉 body diagonals. Below room temperature, magnetite undergoes at least two transitions. At the isotropic point near 130 K, K1 changes sign and the easy axes switch to 〈001〉. Domain structures must change as a result but there is usually little sign of this in the measured sample magnetization.
The Verwey transition (Verwey 1939; Walz 2002) near 120 K is a first-order phase transition. The cubic lattice deforms only slightly and exchange interaction is scarcely affected, as evidenced by the near-continuity of Ms across the transition (e.g., Özdemir 2000; Kosterov 2001), but the magnetocrystalline anisotropy constants of the new monoclinic lattice increase more than tenfold. Ms now lies along an easy c-axis which is one of the cubic 〈001〉 axes. Less reorganization of domains would seem to be required than at the isotropic point, but there are two complications. The anisotropy is no longer multiaxial, with the possibility of 90° walls and closure structures as well as 180° walls (Özdemir et al. 1995), but uniaxial. In addition, within each grain monoclinic twinning typically produces a mosaic of twin domains with different c-axes, minimizing overall crystal strain (Salje 1993).
A variety of techniques have imaged either magnetic domain walls (DWs) (Moloni et al. 1996; Carter-Stiglitz et al. 2006) or twin walls (TWs, the boundaries between twin domains) (Chikazumi et al. 1971; Otsuka and Sato 1986; Medrano et al. 1999), but not both simultaneously. In a recent breakthrough, Kasama et al. (2010, 2013) and Bryson et al. (2013) have imaged interacting DWs and TWs using transmission electron microscopy (TEM). Magnetic structure was obtained both with Fresnel imaging in Lorentz TEM and by off-axis electron holography (Harrison et al. 2002). TWs impede DW motion. When a 180° DW reaches a TW, it cannot pass into a neighboring twin domain whose easy c-axis is rotated by 90°. In addition, the TW is a site of spontaneous lattice strain; magnetoelastic interaction must add to DW pinning (Xu and Merrill 1989).
Indirect evidence for domain reorganization and DW pinning at the Verwey transition is provided by remanence cycling and magnetic hysteresis experiments across the transition region (e.g., Hartstra 1982, 1983; Hodych 1986, 1991; Halgedahl and Jarrard 1995; Özdemir and Dunlop 1998, 1999; Muxworthy 1999; King and Williams 2000; Muxworthy and McClelland 2000; Özdemir 2000; Kosterov 2001, 2003; Özdemir et al. 2002; Smirnov and Tarduno 2002; Muxworthy et al. 2003; Yu et al. 2004; Smirnov 2006, 2009; Kosterov and Fabian 2008). The present paper adds to this body of measurements, filling a data gap between the submicron and mm-size magnetites studied by Özdemir et al. (2002) and complementing the hysteresis study of Dunlop et al. (2018) on the same set of samples used here.
The first purpose of our study was to use well-sized magnetites from a common source (see “Sample characterization and experimental methods” section) to test how low-temperature remanence cycling varies with magnetite grain size. A second purpose was to investigate the effect of internal stress. The ferroelastic properties of monoclinic magnetite (Salje 1993) imply that internal stress should be particularly influential at and below the Verwey transition.
Our samples used natural magnetite single crystals from the Princess Quarry in Bancroft, ON, Canada, a source of museum-quality mineral specimens. Purity of these crystals was tested by X-ray diffraction and the Curie temperature TC. Only the X-ray lines of stoichiometric magnetite were observed; there were no rhombohedral or secondary spinel reflections of hematite and maghemite. TC was 580 °C, the Curie point of stoichiometric magnetite. Identical Curie points were obtained for the crushed sized fractions described below (Dunlop 2014).
Grain size and shape determinations for the magnetite samples
Nominal grain size (µm)
Grain width (µm)
Despite some overlap between size distributions, our samples are probably as narrowly sized as is possible using a dust analyzer. This is an important point because a major objective of this study was to test the variation of magnetic properties with grain size. Maximizing the number of samples obtainable from the available material requires some trade-off with size overlap between samples.
Another purpose of the study was to test the effect of internal stress on magnetic properties. To this end, two sets of samples were prepared. Samples in the first set were unannealed, while samples in the second set were annealed in vacuum for 7 h at 700 °C. Samples were measured as undispersed powders. Previous work (Yu et al. 2004, Fig. 7) has shown very little difference in the hysteresis properties of bulk powders and 0.5% dispersions of synthetic magnetites ranging from 0.24 µm to 16.9 µm in size, presumably because interacting particle clumps are very difficult to break up.
Temperature cycling of saturation isothermal remanent magnetization (IRM), imparted at either 300 K or 10 K, was performed using Quantum Design Magnetic Properties Measurement Systems (MPMS) with SQUID (superconducting quantum interference device) detectors at the Institute for Rock Magnetism, University of Minnesota and at the Department of Earth Sciences, Kyoto University. The dependence of IRM intensity on magnetic field strength was also measured using the MPMS.
Isothermal remanence as a function of field strength
The magnetocrystalline anisotropy and magnetostriction constants of monoclinic magnetite below the Verwey transition (TV ≈ 120 K) are more than an order of magnitude higher than those of cubic magnetite above TV (Bickford et al. 1957; Syono 1965; Abe et al. 1976; Tsuya et al. 1977; Kakol et al. 1991, 1994). The result is that isothermal remanence requires much higher fields to reach saturation below TV than above (Fig. 1). The spectrum of coercivities measured at 10 K extends at least as high as 5 T, while at 300 K a field of 0.2 T will saturate the IRM. In what follows, saturation IRM was produced by a 2 T field at 300 K and by a 5 T field at 10 K.
Temperature cycling of 300 K saturation remanence
Transition temperatures TV estimated from points of steepest descent in first crossings of the Verwey transition, while cooling 300-K SIRMs and warming 10-K SIRMs
Grain size (µm)
TV (K), cooling
TV (K), warming
A small loss of remanence continues below TV but the cooling curves level out below 80 K. In the warming half-cycle from 10 K, the remanence is almost unchanging until 100–110 K and then recovers a small amount—the so-called memory—in passing from the monoclinic to the cubic phase at TV. For the 14 µm sample, there is a small dip and recovery of remanence around 115 K, close to TV = 118 K measured in cooling. This dip is not seen for smaller grain sizes.
Temperature cycling of 10 K saturation remanence
Low-temperature memory ratios
In the early days of paleomagnetism, low-temperature demagnetization (LTD) by zero-field cycling through TV was widely investigated as a nondestructive means of selectively cleaning low-stability remanence carried by magnetite (e.g., Ozima et al. 1964; Creer and Like 1967; Kobayashi and Fuller 1968; Merrill 1970). The idea of continuous tracking to delineate the temperature spectrum of demagnetization came much later (e.g., Dunlop 2003). In the 1990s, memory ratios of remanence intensity before and after LTD were linked to magnetite grain sizes in two careful studies by Heider et al. (1992) and Halgedahl and Jarrard (1995) and proposed as a potential granulometric tool. Although this suggestion was not put to much practical use in the years that followed, it is interesting to test the idea using the data from the present paper.
Is there a phase transition at 50 K?
The IRM acquisition curves of Fig. 1 show that monoclinic magnetite at and below 50 K has a spectrum of coercivities 10–20 times harder than that of room temperature cubic magnetite. This observation fits with measurements of the temperature dependence of coercive force Hc (Dunlop et al. 2018, Figs. 5, 6) in which Hc increases by a factor of ≈ 5 after cooling the sample through the Verwey transition, and by a further smaller amount below 50 K. Is there a true phase transition at 50 K or is this a point at which anisotropy and/or magnetostriction constants begin to increase? There is no indication of a sudden change in anisotropy or magnetostriction around 50 K in the data of Abe et al. (1976) or Kakol et al. (1994), but it is evident in Fig. 1 that individual coercivities are almost twice as large at 10 K as at 50 K.
Magnetic susceptibility undergoes changes below 40–50 K which are not generally manifested in remanence data (Muxworthy 1999; Kosterov 2003; Özdemir et al. 2009). Magnetic viscosity is also affected (Muxworthy and Williams 2006). These effects are usually attributed to diffusion after-effect and disaccommodation of susceptibility rather than to any phase transition (Walz 2002; Walz and Kronmüller 1991).
In the warming curves of 10-K saturation IRM for the annealed magnetites (Fig. 7), the three finest grained samples (1, 6 and 9 µm) have a clear inflection at 50 K between a segment of rapid remanence loss from 10 to 50 K and a more slowly descending portion from 50 to 80 K. However, this inflection is doubtful for 14 µm and larger magnetites and is completely absent from the corresponding unannealed magnetite warming curves. It is also absent from the cooling or warming curves of 300 K saturation remanence for the 1, 6 and 9 µm samples (Fig. 2). Thus, 50 K likely does not mark a structural change in magnetite, which should manifest itself in originally cubic magnetites transformed to monoclinic by cooling to 10 K, but the end of a rapid decline in coercivity that unpins about 20% of the remanence of monoclinic grains magnetized at 10 K. Why coarser annealed grains and all the unannealed magnetites are unaffected is unclear.
Cycling room temperature remanence through the Verwey transition
The Verwey transition is well expressed in all remanence cycling experiments (although the isotropic point is invisible, as in most previous studies). But its expression depends on grain size, annealing, and the nature of the phase given the initial remanence—monoclinic or cubic.
Remanence given to cubic magnetite at 300 K is already reduced by 70–80% at TV = 115–120 K (Fig. 2) because of the steady decline in anisotropy and magnetostriction over this temperature range (Hodych 1986; Özdemir 2000). In the next ≈ 20 K of cooling, the remanence continues to change on a smaller scale, as do the magnetic hysteresis parameters of these same samples (Dunlop et al. 2018, Fig. 7). The Verwey transition has a sharp onset, as monoclinic phase nuclei appear and their boundaries propagate rapidly, but the disappearance of the cubic phase does not mean the end of all change. Kosterov and Fabian (2008) found that below TV, more frequent and larger jumps occurred in M vs. T curves of individual grains compared to above TV. The main mechanism of change is likely the continuing evolution of the mosaic of monoclinic twins and their TWs (Kasama et al. 2010, 2013). DWs trapped within twin domains and pinned at twin boundaries can move limited distances as the twin domains shift their positions and sizes. Arrays of mobile 180° DWs observed by Kasama et al. (2013) in occasional large untwinned monoclinic regions may also play a role.
More intriguing and not explained in any obvious way are the remanence minima centered on TV in 14 µm and larger annealed magnetites (Fig. 3). These become quite accentuated in the 110 and 135 µm annealed samples and in a 1.5 mm magnetite crystal (Fig. 5), where they appear in both cooling and warming half-cycles, evidence that the underlying magnetoelastic phenomena causing them are reversible. What could be causing the remanence to spontaneously increase in cooling through the 15–20 K interval below TV and to decrease even more markedly in the warming half-cycle?
Although not remarked upon in any detail in most cases, similar magnetization dips and recoveries have been observed previously in cycling 300-K remanences (Hartstra 1982, 1983; Halgedahl and Jarrard 1995; Özdemir and Dunlop 1999; Muxworthy and McClelland 2000; King and Williams 2000; Özdemir et al. 2002; Kosterov 2003). They are usually associated with the larger grain sizes. In Hartstra’s studies of sized crushed magnetites, dip and recovery was well developed in 150–250 µm, 100–150 µm and 25–30 µm grains, just detectable in 10–15 µm grains but absent from the data for < 5 µm grains. Kosterov (2003, Fig. 2), using two of Hartstra’s HM4 magnetites, found a similar result. These observations accord well with ours.
Halgedahl and Jarrard (1995) detected a dip and recovery below 120 K only in a mm-size crystal. There was no remanence dip in any of their glass–ceramic magnetites, spanning sizes of 0.2, 1.5, 7 and 100 µm. Glass–ceramic magnetites (Worm and Markert 1987) are well known to have high internal stresses because of their confinement in a glass matrix, and indeed we observe in the present study that internal stress in unannealed samples reduces the dip-and-recovery effect, particularly in the cooling curve (Fig. 4).
On the other hand, in studying low-stress hydrothermal magnetites Muxworthy and McClelland (2000), reported well-developed minima, mainly in warming curves, for 3 µm, 7.5 µm and 39 µm grains but a very muted effect for 108 µm grains. A natural 190 µm magnetite, however, had remanence minima in both cooling and heating. Özdemir et al. (2002), studying even finer hydrothermal magnetites with mean sizes of 37, 100 and 220 nm, found minima at TV in cooling curves, but more prominent were large irreversible drops in remanence between 100 and 115 K on rewarming the samples, with little or no recovery above TV.
The bulk of the evidence favors magnetites with low internal stress and grain sizes > 15 µm as the typical natural candidates for remanence rebound just below TV. Thus, stress, which favors stronger DW pinning, inhibits the phenomenon, while grain sizes above the nominal pseudo-single-domain (PSD)-multidomain (MD) boundary promote it, presumably for the same reason: larger numbers of more mobile DWs. Smirnov (2006) and Roberts et al. (2017) argue that the PSD state is a physically distinct magnetic state and not a mix of single-domain (SD) and MD states as modeled by Dunlop (2002). In either case, most of the grain sizes typically displaying dip and recovery are large enough to contain at least a few well-developed DWs.
The rebound of remanence in cooling below TV is reminiscent of the memory phenomenon, in which a certain fraction of the initial 300-K remanence is recovered in the second passage through TV. One difference is that memory persists in warming to room temperature, whereas the rebound gain of remanence is largely transitory and disappears with further cooling. Muxworthy and McClelland’s (2000) explanation for the rebound, which they call a positive anomaly, is the removal of screening soft DWs, revealing a hard domain structure carrying a net moment in the direction of the initial remanence. While this might be reasonable for the PSD-size hydrothermal grains that display the anomaly in their sample set, it is doubtful for the larger MD-size natural magnetites that more typically show rebound in other studies, including ours. Also if screening walls in the cubic phase are removed at TV, why should the positive anomaly persist as the monoclinic twin and domain structures evolve during a further 15–20 K of cooling?
Cycling low-temperature remanence through the Verwey transition
Cubic magnetite magnetized at 300 K has already irreversibly lost 70–80% of its saturation remanence when it reaches TV. Little remanence is lost in crossing TV; indeed more typically remanence is gained. In contrast, monoclinic magnetite magnetized at 10 K loses only 10–25% of its saturation remanence in warming to 100 K, but a further 50–80% disappears between 100 and 120 K (Figs. 6, 7). The plunge is particularly precipitous for annealed samples with more easily unpinned DWs where up to 70% of the remanence disappears in the interval 105–115 K (Fig. 8). There is no sign of any dip and recovery at or near TV.
Domain states change with temperature in both cubic and monoclinic magnetite as a result of changes in anisotropy. For example, our 6 µm annealed magnetite sample has PSD hysteresis properties when magnetized in the cubic phase at room temperature, but its hysteresis properties are MD as it approaches TV (Dunlop et al. 2018, Fig. 9). In the monoclinic phase, it rapidly hardens and when it reaches 10 K it has the hysteresis properties of a small PSD grain, approaching SD size. Thus, all our samples when magnetized as monoclinic magnetite at 10 K have more PSD- or SD-like behavior—fewer and/or less mobile DWs—than they have when magnetized as cubic magnetite at 300 K. This helps explain why so much more of the cubic phase remanence is demagnetized when cooled to TV than the corresponding monoclinic phase remanence when warmed from 10 K. In turn, the contrasting signatures in crossing TV are determined by the amount of remanence remaining to be demagnetized on reaching the Verwey transition region—most of the 10-K remanence but virtually none of the 300-K remanence. Unfortunately, the massive demagnetization of the monoclinic phase remanence masks any subtle details like those we see in the cubic → monoclinic transformation.
The Verwey transition temperature TV at which the structural transformation occurs has some variability (Table 2). For annealed samples, apart from two rather uncertain determinations, TV measured in cooling 300-K saturation remanence decreases steadily with decreasing grain size from 120 to 122 K for the 110 and 135 µm samples to 112 K for the 1 µm sample. On the face of it, this might be taken as evidence for some degree of oxidation of the finer grain sizes but there is no corresponding trend in the TV values determined from warming curves of 10-K remanence, which are uniformly 110–114 K. On the other hand, unannealed samples have higher TV values than the annealed samples, almost all close to 120 K.
Memory and memory ratios
Memory is the spontaneous recovery on a second crossing through TV of some fraction of the remanence that was lost on the first crossing. In Fig. 2, the 1, 6 and 9 µm samples have small memories after warming: Their remanences above TV and at room temperature are higher than they were below TV. The 14 µm sample has a dip in remanence at TV, then a modest recovery with further warming, but the remanence at 300 K is scarcely larger than it was at 100 K: the memory is negligible.
Memory of low-temperature remanence is not paleomagnetically useful but is interesting nonetheless. In Fig. 6, the unannealed magnetites without exception have no memory: The remanences at 10 K after a full warming–cooling cycle (the individual points near the left axis) are identical to the half-cycle remanences measured at 300 K. The annealed magnetites do have significant memories (Fig. 7); the fractional remanences recovered between 300 K and 10 K being smallest for the 1 µm sample and largest for the 135 µm sample. Thus, low-temperature remanence of monoclinic magnetite does preserve some memory of its original domain configurations after conversion to the cubic phase and back. To our knowledge, this behavior has not been noted before.
The mechanism of conventional memory—that of room temperature remanence of the cubic phase—has been clarified by the TEM observations of Kasama et al. (2013). Their initial Lorentz images at 143 K showed large magnetic domains separated by 90° or 180° DWs. At 103 K after zero-field cooling, the domains were smaller and were separated by 180° DWs. In spite of the change of phase and anisotropy, there was a good correspondence between magnetization directions observed (from electron holograms) above and below TV, particularly near the specimen edge where self-demagnetizing effects come into play. In the final remanent states recorded after zero-field warming back to 143 K, large domains redeveloped. Despite some differences in positions of specific DWs, the overall pattern of domains and magnetization directions roughly matched that seen initially at 143 K.
It seems clear that the uniaxial domain structure in the monoclinic phase below TV preserves a template sufficient to renucleate a partial replica of the initial multiaxial domain pattern on rewarming above TV, as has long been speculated in the literature (e.g., Kobayashi and Fuller 1968). The directional stability of saturation remanence in cycling through the Verwey transition (Smirnov and Tarduno 2011) lends further support to this model. If the monoclinic phase can act as a bridge preserving overall memory of cubic phase remanence, it seems likely that the dip and recovery of remanence (or “positive anomaly”) at and immediately below TV is also a result of linkage between domain structures on either side of the transition. Detailed observations of domain structures within 10–15 K of TV are needed to test this idea.
We have made a systematic study of remanence cycling as a function of grain size in magnetites ranging from small PSD (≈ 1 µm) to moderate MD (100–150 µm) sizes and a less thorough investigation of the effect of internal stress, through the use of matching unannealed and annealed sample sets. The magnetites all originated from natural pure crystals. Internal strain resulted from varying amounts of crushing and milling before separation into size fractions. Our results are compatible with those of previous studies of crushed natural magnetite (Hartstra 1982, 1983; Kosterov 2003) but differ significantly from observations on high internal stress glass ceramic magnetites (Halgedahl and Jarrard 1995) and low-stress hydrothermal magnetites (Muxworthy and McClelland 2000; Özdemir et al. 2002).
A possible phase transition from monoclinic to another phase of magnetite around 50 K seems more likely to be a temperature at which the anisotropy and/or magnetostriction constants begin to increase. The evidence against a transition is that only the finest annealed grains (< 9 µm) have a convincing inflection in their 10-K remanence warming curves at this temperature, that unannealed grains of all sizes have no indication of such a transition, and that cooling and warming curves of 300-K remanences for all samples also lack the transition. Coercive forces of the finer grained magnetites increase around 50 K (Dunlop et al. 2018, Figs. 5, 6), although they do not continue to increase at lower temperatures. However, IRM acquisition curves show that the entire spectrum of coercivities is multiplied almost two-fold between 50 and 10 K (Fig. 1).
One of the striking features of our cycling experiments is the very different behavior of monoclinic magnetite when it is magnetized at low temperature and warmed in zero field through TV as opposed to being magnetized as cubic magnetite at room temperature and converted to monoclinic magnetite by zero-field cooling through TV. Previous authors have remarked on this contrast (e.g., Muxworthy and McClelland 2000), but it is less surprising when the contrasting domain structures and anisotropies at 10 K and 300 K are taken into account. Hysteresis results (Muxworthy 1999; Özdemir et al. 2002; Dunlop et al. 2018) show that domain structure becomes more MD-like as magnetite’s anisotropy and magnetostriction decrease en route to TV, then abruptly revert to PSD-like in the much higher anisotropy monoclinic phase below TV, ultimately approaching SD-like behavior at 10 K. In the simplest terms, DWs abound and move readily when cubic magnetite is cooled from 300 K; at TV there is little or no remanence remaining to be demagnetized. But when monoclinic magnetite is warmed from 10 K the few DWs available are strongly pinned at twin boundaries or crystal defects; massive demagnetization can only occur with the massive drop in anisotropy and infusion of new mobile DWs near TV. Although simplistic, we believe this is the basic reason for the contrasting cycling curves of Figs. 2, 6 and 7.
An interesting and unexplained detail of some cycling curves of room temperature remanence is a small to pronounced minimum at TV, particularly in warming curves (Figs. 3, 4, 5). Where the minimum is well developed there is an accompanying peak in both warming and cooling curves centered on 100–105 K. In cooling, this represents a spontaneous recovery of remanence lost in crossing the Verwey transition. This dip-and-recovery phenomenon has been widely observed but not convincingly explained. It is absent from samples with significant internal stress and from natural magnetites below about 15 µm in size. But artificial magnetites produced in a low-stress hydrothermal environment exhibit dips and peaks near TV in small grains and lack them in ≈ 100 µm grains (Muxworthy and McClelland 2000; Özdemir et al. 2002). The key may lie in the rather unexpected similarity between uniaxial monoclinic magnetization directions below TV and the corresponding cubic multiaxial patterns and Ms vectors above TV, as demonstrated by Kasama et al. (2013). What is recovered on a small scale over a few tens of degrees can evidently be retained as remanence memory over the broad temperature range of the entire cycling experiment.
Remanence memories are rather small for our samples if memory is taken to be strictly the recovery of remanence between the monoclinic and cubic phase on the second passage of TV. A more utilitarian definition would be simply the fraction of initial remanence that survives the double passage through TV, and is available for paleomagnetic measurement. From this viewpoint, our samples retain respectable working memories, ranging from 20 to 40% for the 1–14 µm annealed samples. It is interesting that the same samples also have measurable although smaller memories, by either definition, when given a saturation remanence at 10 K and cycled to 300 K and back (Fig. 7). Unfortunately, the various memory ratios are too scattered as a function of grain size to have potential as granulometric indicators (Fig. 9).
DD as the senior author gathered the majority of the data and did most of the writing of the manuscript. ÖÖ participated in the data gathering and ongoing discussions of the meaning and interpretation of results. Both authors read and approved the final manuscript.
Research supported by the Natural Sciences and Engineering Research Council of Canada. Thanks to Mike Jackson, Bruce Moskowitz and Peat Sølheid for their discussions and help during our visits to the Institute for Rock Magnetism, which is operated with support from the National Science Foundation, Earth Sciences Division and the University of Minnesota. Measurements at Kyoto University were taken during a visit funded by the Japan Society for the Promotion of Science. We thank Prof. Masayuki Torii for hosting our visit and participating actively in the measurements. Constructive reviews by Aleksey Smirnov, Andrei Kosterov and Adrian Muxworthy improved the paper. As stated in the Acknowledgments, Mike Jackson, Bruce Moskowitz and Peat Sølheid of the staff of the Institute for Rock Magnetism, University of Minnesota, helped in setting up experiments and informal discussions of the data but did not participate actively in the data gathering and final interpretation. Prof. Masayuki Torii took a more active role in the measurements at Kyoto University because of his greater experience with the instruments used. He has, however, specifically declined to be included as an author on the paper. All these colleagues are agreeable to being acknowledged.
The authors declare that they have no competing interests.
Availability of data and materials
The datasets used and/or analyzed during the current study are available from the corresponding author on reasonable request.
The sources of funding for the research reported were the Natural Sciences and Engineering Research Council of Canada (Grant No. A7709) and the Japan Society for the Promotion of Science, as declared in the Acknowledgments. Neither funding body had any direct influence on the design of the study or the collection, analysis and interpretation of data or on the writing of the manuscript.
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